Polymers for anticorrosive coatings

CONSTAKOR® proprietary anticorrosive materials

In 2007, Constanta-2 registered the trademark Constakor® comprising a number of materials designed in cooperation with Volgograd State Technical University. Constakor series includes proprietary cold- and hot-set rubberizing compounds and the anticorrosive coating resurfacing and conditioning compositions. Application technique of most liquid materials is quite simple and user-friendly, with minimum requirements to surface preparation and personnel qualification. This saves the time and ensures high reliability of the resulting protective coat. Coatings with Constakor® demonstrate 10 to 15 years of excellent performance and high chemical resistance.

The product line we offer is a good anticorrosion solution for power industry, food-processing, chemical, petrochemical, metallurgical and machine-building plants. Manufacturability and easy application of the coatings facilitate and improve the quality of anticorrosion works. For several years, Constakor proprietary coatings have been successfully used both to protect new equipment and renovate existing installations.

Cold-set protection materials:

tep 1

Constakor TEP® (Patent No. 2315075, TU 2513-003-34244672-2007) is a two-component cold-set rubberizing compound based on diene styrene thermoplastic elastomer and intended for the coatings rated to рН 2-14 at -15°С to +95°С. The compound has been designed to replace rubberizing sheets in the protection of different vessels, for instance solution storage tanks, chemical water treatment tanks, pipelines and the anion-exchange, cation-exchange and combined-action filters. Constakor-TEP can be applied even to heavily pitted metal and concrete surfaces.

This material applies in 8 to 10 coats, each coat being dried up to 800 µm, to obtain a resulting coating similar in its performance to the conventional 3.5 to 4 mm thick rubber sheeting.

New equipment can be factory-coated and shipped at temperatures to -25°С.

Service life: 10-15 years.

Constakor-TEP can be used as a sole coating material or as the main component of Constakor and Constakor LIGHT anticorrosion systems. Constakor anticorrosion system is a three-component protective coating extending the service life of the equipment. It is recommended for factory-coating of new vessels to be shipped to and stored at the final location. The components are Constakor-Primer for maximum adhesion, Constakor-TEP for protection proper, and Constakor-Protect enamel for preservation before putting into operation. This system can be applied to equipment exposed to more severe conditions (e.g., concentrated solutions, moderate abrasion).

CR-TEP reactive diluent (TU 2435-021-34724672-2015) - текст

Constakor LIGHT is the anticorrosive coating option recommended for equipment operated in gentle conditions with low corrosiveness and zero abrasion, for instance, neutralization tanks. Constakor LIGHT system consists of a primer coat and 4 to 6 coats of Constakor-TEP instead of the conventional 8 to 10 coats. This significantly saves materials, labor and costs.

Table 1. Constaktor-TEP resistance to some corrosive chemicals

Chemical Maximum concentration, % Maximum operating temperature at specified concentration, °С
Nitric acid 5 20
Sulfuric acid 70 70
Hydrochloric acid Concentrated. 20
Phosphoric acid Concentrated. 70
Sodium hydroxide Concentrated. 70
Sodium chloride 100 70
Calcium hydroxide 100 65
Potassium (sodium) bichromate 10 70
Zinc chloride 50 65
Calcium phosphate, hydrogen phosphate 10 25
Calcium chloride 10 25

Constakor–AQUA® (TU 2513-014-34724672-2010) is a single-component rubberizing composition based on Constakor-TEP and intended for metal surfaces of potable/sanitary water facilities. The edge over other available epoxy compositions consists in a higher resistance to acids and alkalis, improved elasticity enabling to maintain vessel protective coating’s continuity despite operational strains, durability resulting from enhanced mechanical and adhesion strength and good resistance to erosive action of the fluid (slurry).

Operating media are as for Constakor TEP above; operating temperatures: -15°С to +60°С.

Safety and Health Certificate for the material is available.

Application is similar to painting. For maximum performance and durability of the coating, the protective composition should be underlain with Constakor-AQUA primer.

Constakor SEBS® is a single-component rubberizing material intended for metal surfaces exposed to acids, alkalis (see the table) and oxidizing solutions (hypochlorites, 20% nitric acid) at -15°С to +95°С

Cold-set touch-up compound Constakor-Prom® is a two-component composition designed for spot repair and resurfacing of rubber coatings. This is the quick and efficient way to return the equipment to operation.

Hot-set rubberizing materials:

Constakor SKMS - improved rubber sheets for conventional rubber coating. Constakor SKMS sheets are designed for chemical water treatment facilities exposed to continuous abrasion.

Constakor–EXTREME Line® - hydrocarbon rubber (chlorobutyl rubber) sheets. Constakor–EXTREME Line coatings are designed for the etching and metal-coating (for instance galvanization) equipment and tanks at metallurgical facilities; water treatment equipment at power-generating and machine-building plants; chemical and petrochemical factories. The coatings can withstand occasional or continuous action of highly corrosive fluids, e.g. inorganic acids and solutions, acid mixtures and oxidizers, at high temperatures. The table below provides details of fluids and operating modes for the equipment protected with Constakor-EXTREME Line.

Table 2. Fluids and operation modes of Constakor-EXTREME-Line-coated equipment

Fluid temperature, °С Fluid composition Corrosive action
15 - 75 Mixture of dissolved hydrofluoric and hydrochloric (or hydrofluoric and nitric) acids Occasional High impact and vibration loads, abrasion, pressures
50-75 Continuous
15-30 Concentrated hydrofluoric, sulfuric, hydrochloric, nitric acid, chromic acid mixture Continuous
15-100 Ferrous ions containing mixture of dissolved hydrofluoric, sulfuric and nitric acids Occasional

Constakor–EXTREME Line rubber coatings have demonstrated reliable performance and longer than 10 years’ service life..

Constanta-2 anticorrosion treatment systems for power-generating, petrochemical, chemical, food-processing facilities, mineral fertilizer manufacturers, galvanizing shops and other applications involving corrosive actions

№ п.п. Equipment Corrosive fluid/environment Anticorrosive system. Coating service life proved by experience
Chemical water treatment
1 Clarification tanks, clarified water tanks, decarboniser tanks, decarbonized water tanks Water with up to 10 mg/l dissolved oxygen, pH 2.5-10 EP-KhP; EP; Constakor-TEP, Constakor-Prom, KhSPE, Constakor-N
2 Chemically purified/desalted water tanks Water with up to 10 mg/l dissolved oxygen, up to 5 mg/l dissolved carbon dioxide, рН 6.5 ED-20G, EKhD-G, EN-6-G. Min. 5 years
3 Mechanical filters Water with up to 10 mg/l dissolved oxygen, abrasive EP, Constakor-TEP, Constakor-Prom, Constakor-AQUA
4 Hydrogen cation-exchange filters Up to 5% sulfuric acid solution with to 10 mg/l dissolved oxygen and to 600 mg/l dissolved carbon dioxide, рН 2.0 Constakor-TEP, Constakor-Prom, rubberizing. Min. 5 years
5 Anion-exchange, sodium cation-exchange, combined-action filters Up to 4% alkali solution, up to 4% acid solution, up to 10% common salt solution, up to 10 mg/l dissolved oxygen , рН 4.0-14.0 KhS-KhV, KhS-KhS, ER-KHP, ER, Constakor-TEP, KhSPE, Constakor-Prom, rubberizing. Min. 5 years
6 Neutralization tanks Water with sulfates, sodium chlorides, calcium chlorides, hydrochloric acid, caustic soda, lime ER-KHP, KhSPE, Constakor-TEP, Constakor-Prom
7 Tanks for dissolved sulfuric or hydrochloric acid, alkalis Dissolved sulfuric or hydrochloric acid, caustic soda Constakor-TEP, Constakor-Prom, Constakor–EXTREME Line, KhSPE, rubberizing. Up to 5 years
Thermal equipment
8 Deaerators, drain tanks, condensate storage tanks, industrial condensate vessels Desalted water, condensate with potential (mineral/organic) oil content ER-KHP, ED-20G, EKhD-G, EN-6-G. Up to 5 years
Pipelines
9 Pipelines Dissolved sulfuric acid, hydrochloric acid, salts, petroleum products, water Constakor-TEP, Constakor-N, rubberizing, EP, KhS-KhV, UR, TsVES, B-EP, PP, PEVD, fluoropolymers
Building elements
10 Floors, foundations, drains Variable environment, spilled corrosive fluids System 57-40, tile lining, polymer-concrete floor
Chemical water treatment for open heat supply systems
11 Decarboniser tanks, soft water tanks, H cation-exchangers, pipework Water: total hardness 10 mg/l, carbonate hardness 5 kg-equ/l, weak acid medium, рН 5.5-7.0 Certified materials: ER-KHP, ED-20G
Heat- and cold insulation
12 Storage tanks, pipelines, industrial buildings and facilities Atmosphere, -70°С to +150°С PUF spray, PUF covers, rockwool plates
Electroplating
13 Chrome-plating, zinc-plating, nickel-plating baths 350 g/l chromic anhydride, up to 10 g/l hydrochloric acid, zinc cyanide, 9% sodium hydroxide, etc. System 57-40, Constakor–EXTREME Line, PP, PVC 2
14 Etching, passivation and rinse baths 38% hydrochloric acid, 15% nitric acid, 40% sodium hydroxide, electroplating bath solutions, acids, alkali PP, PVC
Etching rooms at pipe rolling plants
15 Electroplating and passivation baths 40 g/l hydrofluoric acid, 120 g/l nitric acid, 120 g/l sulfuric acid Constakor KhBK, SKEPT
Food processing
16 Processing and storage tanks for alcohol-containing products Up to 400 g/l ethyl alcohol, 40°С Epovin, Constakor-AQUA
17 Processing and storage tanks for alcohol-free products Weak food acids, 40°С Constakor-AQUA, B-EP, Epoben
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